Well I don't just want to do the pool thing, I want to create casino games. The pool was only an idea.
Should I make roulette, black jack, poker, etc?
Who is your target audience? I suspect that a lot of people are going to be more willing to play games which involve some degree of strategy, like poker and black jack, than games of pure chance.
The online poker community has taken some serious hits recently so people are looking for new places to play and new ways to fund playing (there's actually a thread about Bitcoins on one of the bigger online poker forums). On the other hand, the recent dramas in the online poker world mean that establishing trust is going to be a major issue for new providers, so you'd need to think about how you're going to do that.