There are a few problems with this.
The first problem is that there are too many people who think they have god on their side. They don't care about dying, because they think there is something waiting for them beyond death. And they don't care about the carnage, because any atrocity can be justified by calling it the will of god.
The second problem is that some people just want to watch the world burn and some people just want humans to stop existing. The church of Euthanasia for example.http://en.wikipedia.org/wiki/Church_of_Euthanasia. There are many other extremists who hold a similar position.
The problem is that as the rate of technological progress increases and information becomes more available, it becomes easier and easier for a few wackjobs to seriously threaten the human population using various means such as desinger virus or nuclear power. There are probably a lot of private labs in world who have the materials and personnel necessary to design a virus that could serious threaten the human population.
I don't think such weapons make humanity safer. The threat of total extinction is increased because of them. They might encourage peace but they raise the stakes to such an extent their benefit is not worth the risk that they introduce.