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I question whether multiple currencies could co-exist. Nobody wants to receive payment in a currency that has less CPU hours of proof-of-work. If the cryptographic math behind bitcoin makes sense, then people will want to be paid on the proof-of-work that represents the most widely-trusted transaction history, which will usually equate to the proof-of-work with the most blocks / CPU time.
Multiple anonymous currencies already do co-exist. Operationally, there is nothing special about Bitcoin; it is just one more currency that can be used in the same way as Pexunix, LR, etc.. The only difference is that Bitcoin is distributed and not administered by a central authority, but that detail may not necessarily concern the average user.
If alternative distributed anonymous currencies spring up, there is no reason that they can't be exchanged for Bitcoin, just like traditional non-distributed currencies. If the alternative currency has less CPU hours of proof-of-work than Bitcoin, then the exchange rate will reflect this.
The other currencies you listed (Pecunix, LR) are backed by gold and silver via the USD or EUR, so they are not really new currencies as much as more anonymous forms of paypal. Other e-currencies I have run into over the past couple years are also usually backed by gold or silver ultimately.
Bitcoin, in contrast, does not derive its value from gold and silver. Instead, bitcoin derives its value from the same things that give gold and silver its value. It:
1. is suitable for transactions
2. has limited quantity (scarce)
3. is not arbitrary: it is the currency that has the most widely recognized transaction history, measured by CPU time
I can imagine there being 2-3 different CPU-based currencies like bitcoin with exchange rates as you said, but it would be better for only one such currency to exist to preserve the non-arbitrary nature of the leading currency and promote its legitimacy, which everyone using bitcoinlike currencies will want. I would expect a self-perpetuating tendency toward only one CPU-based currency.