Based on my experience with those motherboards.
ProcessorIf you plan to use 4th Gen i3,i5,i7 it would be better, but G series (I'm using G3260) it's more than enough for me.
RAM4GB it's enough, 8GB would be better, 2 x 8Gb Excellent, but overkill.
PSUsSingle 1200 Watt PSU seems safer, cause we need power spare to keep our devices in a good condition. Remember, mining for long terms. But you have prepared your PSU, double PSU 850+550, and it would be more than enough, pay more attention to powering scheme.
Riser Power ConnectorsMolex and 6Pins safer that SATA (from how much power that can be handling), but isn't mean that SATA un-useless. If you are using SATA, make sure limit it to max two2 Riser powered by one rail SATA connector, would be better one Riser on every one SATA rail connector.
1x to 4x expander cardPersonally, I didn't recommend for using 1x to 4x expander card. Would be giving you more trouble.
Do I will face any problem using Pentium for 6 or more GPUs ?As long as you following all of the essential rules (Giving enough power, a right powering scheme, picking a right driver..etc), You'll go smoothly.