I had a 2 of 3 multisig and tested them successfully years ago when I installed Electrum 2.3 for windows. That is, I have to use 2 wallet to co-sign a spending.
But tonight I updated to 2.6.4. Then when I tried to send BTC, there is no co-sign button. And once I entered the password. The BTC just went out successfully and received successfully by designated address.
How to make my Electrum multisig again?
I assume you restored using your seed ? I guess that's what took off the multi-signature (I know this what happens when you are using 2FA)
Just make another new wallet and you should be fine .