So you are asking which is less likely to get infected?
[a] RasPi (cold storrage) & Win7/8 (Hot storrage) vs. [c]* RasPi (cold) & Dedicated (Linux) machine with Electrum (Hot)
Since most viruses or trojans nowadays rely on userinteraction [c] is more secure. Yes, even Windows is on a securitylevel that makes an infection without interaction from the user very unlikely.
If you are willing to make the sacrifice in money (need an extra machine) and comfort (need to boot that extra machine everytime you want to spend money) aswell as time (need to setup that extra machine) [c] is the way to go. I assume here that you have a reasonable amount to protect. IMHO its overkill for 1 btc, unless you enjoy setting up systems
* I wanted to use [a] and
but since thats short for bold, its c now.