ATI 5xxx and 6xxx work best with different driver versions than 7xxx, so it is best to stick these two series of cards in different machines so you can optimize performance for each.
The earlier cards will work best with 11.6-11.11 Catalyst with RAM underclocked to ~300MHz, the 7xxx cards need newer drivers. Using the newest 13.x drivers will bork OpenCL mining on older cards.
6670 is just a passable card anyway:
480 Stream Processing Units
24 Texture Units
(for reference, it's the card in front:)