If you have enough molex/sata connectors, you can use a molex to 8pin adapter/converter to each rail.
Make sure to use only one rail per GPU and a good quality adapter.
However four (4) 185W GPU is a bit an overload for a 750W PSU.
You can go for 3 RX580 for each PSU.
I did order a sata 6 pin to PCIE dual 6+6/2 pin cable (my cards take both 6 and 8 pin connectors to run)
Once I had the cable plugged in to the SATA port on the PSU and tried to power on the mining rig, that power supply and anything I had connected to it would turn on for 1/2 a second and then immediately shut off