As I thought.
And it wouldn't help you at all if it could be done. What you should do is make a 1-of-2 multisig address and send to it now instead of later. If these other keys are more secure than the key that is receiving the money (like on a webserver), you should move the funds out quickly.
It would help. It means the network would verify that the money can only be sent to one of two addresses. A third-party would have no interest in hacking the keys because they still wouldn't be able to send the outputs to their wallet. They would have to hack the keys for the transaction and the keys for one of the destination wallets, at least, and the latter can be cold wallets.