But the question remains: is 99% randomness significantly better than 90% randomness?
Yes, clearly. If I can predict what you would choose 1% of the time versus I can predict what you would choose 10% of the time, then that's an order of magnitude difference.
We might not be as fast, but our brains are incredible at contemplating and imagining the concept of randomness!
They really aren't. There is no evolutionary advantage to imagining or visualizing completely abstract random numbers. There is, however, a strong evolutionary advantage to noticing patterns, sequences, order, and so on. Our brains are hardwired to be ordered and logical, which is why we are so terrible at picking random numbers and why there are tens of thousands of examples of brainwallets being hacked.