How is one going to buy let's say a car underground? Cars have to be registered, etc. Transactions above certain amounts have to be registered, etc. How is Bitcoin or an alternative system going to get around that? For digital goods one could use Bitcoin, but most interesting goods are not digital.
Well, if you want a new Mercedes Benz or something like that, then you will need to buy it in the old economy. However, I could envision a resourceful agorist buying an old clunker with some national currency and restoring it to like new condition and then selling it for Bitcoins. When you register the car, which would already have a title, you would only have to pay taxes on its old, unrestored value.
In the future, there will be a greater availability of desktop manufacturing devices and eventually molecular manufacturing machines, so the percentage of the world economy that can be delivered digitally is only going to increase.