I wouldn’t consider it for a second. Even when that game is Barcelona Vs the bottom team on the table. I would feel something is up and something has got to be up else, how do you go for such an odd, it’s oddly. When you find big teams in that situation, you’ll just know they aren’t using there first eleven, probably have their youth team lined up. When it’s with other mid tier teams, then it’s a likely lost bet, I can’t go for such odd with low probability of success.
Most likely, I would never risk betting on such odds in a single bet either, I think they won't even give such odds if Barcelona plays the last team in La Liga, it's more likely if Germany plays against Liechtenstein, and in that case it's clear that they have no chance of winning, so I wouldn't even want to bet $1 on it, because I don't see any point in it.
I'd rather bet with odds of about 2 and bet more money, and know that I have a better chance of winning than bet with huge odds, and understand that such a bet has practically no chance of winning.