1. Is there anywhere I can see a list of the buy and sell order queued on MTGOX in the same way as Vircurex? I am aware of the wall graph but want specific figures.
Clark Moody has a bitcoin view giving the order book with sum total amounts ... if that is what you are looking for:
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http://bitcoin.clarkmoody.com You can also click the calculator on that to see slippage for specific order sizes.
2. If the current MTGOX BTC buy price is $95 and I set a buy order for 10BTC at $100 when I have no USD in my account, what happens when say $1,000 then arrives in my MTGOX account?
Then that is no different from placing a buy order of 10 BTC @ $100 when the deposit gets credited to your account. If there are sell orders that will fill your order, they are matched and you are the new owner of up to 10 BTC at $100 (or less if there were standing sell orders for an amount lower than $100 at the time your funds got credited).