I use XP / 5770x2 / catalyst 11.3 / GUI Miner
I am not going to upgrade to Win7+ for different reasons, and all other drivers I tried either didn't work or resulted in an unstable system.
Which OpenCL SDK?
I can't remember which Catalyst version did and didn't have the 100% CPU bug problem. But the dramatic hash rate problem is something else. I would investigate that independently of the CPU utilization.
That being said, read the CGMiner FAQ on the recommended Catalyst and OpenCL. Also search the CGMiner thread on which Catalyst does NOT have the CPU utilization bug. I have my notes somewhere as I saw them last week. If I find them again I'll post what I was using when I had a similar configuration as yours.
In the mean time you can set your processor affinity for your mining software to only use one core of your CPU, if you have more than one core on this system.
Sam