There is no way you would make any money by mining Bitcoin with your pc. It costs a lot of electricity and the little money you would get out of it would by no means compensate for that.
And with the old cheap hardware it's pretty much the same. It's really competitive. The only way to get some significant work done is to buy high hash rate equipment, but is very expensive. And it's questionable if you ever break even.
Doesn't mean that you don't have to mine, if you want to contribute to the success I encourage you to mine. It strengthens the security of the network.
If you still want to do it, some sites can explain it better then I can do it here. E.g.:
http://startbitcoin.com/