You should never export any private key from your deterministic wallet. If you leak the private keys the other private keys in the deterministic sequence might be calculated
To clarify the private keys alone are not enough. You need the master public key + one or more private keys. But, yes, the risk arising from exposing a private key in a deterministic wallet is greater than doing the same in a non-deterministic wallet. The risk is greater because the master public key is not really protected as such by electrum. Anyone that has access to your system can read the master public key from the wallet file.
oh and one more question:
what´s the purpose of the master key?
I realize that:
-the seed is needed for generating addresses, recovering the wallet...
-the password is needed in order to encrypt the wallet
But what´s the purpose of the master key? Should I make
a backup of it? Or what´s the most common usage for it.
Do I need it at all?
Bitcoin is based on asymmetric encryption so there are two keys behind every address - private and public. The private key has to be kept secret while the public key can be revealed to the world. You can derive the public key from the private key but not vice versa. The address is a hash of the public key.
Stuff encrypted with the public key can only be decrypted with the private and vice versa. Messages signed by the private key can be verified by anyone using the public key. Sending bitcoins is simply signing off ownership using your private key.
In Electrum there are two master keys. The master private key and the corresponding master public key. The master private key is used internally in Electrum and is not exposed in the user interface. It is derived from the seed and extended for each address to create address specific private keys. The master public key can be independently extended to arrive at address public keys. The difference is that with the master public key you can only generate public keys and corresponding addresses not private keys.
You can use the master public key to create watch only wallets. Unlike bitcoin address public keys the electrum master public key should not be exposed to the world at large because, if it were, people could see all your wallet transactions past, present and future. So exposing the master public key leads to a loss of privacy. But you don't need to backup the master public key to secure your coins. The seed is enough.