As long as you set the exact amount to be sent and set the exact fee using the dynamic slider then it will be. Be sure that you have enough balance on your electrum to cover the fee and the amount to be sent or else you will get an error "Not enough Funds"
With the example above, you will send a total of 0.0101 BTC, and the 0.01 BTC will be sent to the receiver. Make sure that you have at least 0.0102 BTC in your wallet.
BTW this thread belongs to Alternative clients > Electrum