Be very careful if you buy bitcoins on Coinbase and Binance as suggested above, Payoneer may suspend your account in no time.
They don't allow transactions related to cryptocurrencies, you can read their policy it is clearly stated. If you use the card, of course, they will know it and so they will terminate your account definitely. And you will never be able to have another one.
I wouldn't even try.
Well said, the third-party transaction will checked by the Poloniex team. I also prefer not to risk the account in this situation.
Instead of directly buying with SimpleX(the main provider for Binance, Myetherwallet, and other exchanges), OP can fund his Skrill, Neteller account and trade the Skrill balance for Bitcoin. Without the middleman, I wouldn't even attempt to test it.