What are the largest databases of pairs (pk,adr) where pk is a private key (whatever format) and adr the corresponding P2PKH address?
I doubt anyone actually bother to create and share such data, when they could just generate it by themselves. If you attempt to search it on google, you probably find directory.io clone that actually generate private key when you open their webpage.
I'm trying to estimate what kind of training data an AI would have.
Maybe this page can help you
https://en.bitcoin.it/wiki/Technical_background_of_version_1_Bitcoin_addresses. Note that uncompressed and compressed WIF private key generate different Bitcoin address.