I see. So, if I'm understanding you correctly, the only variable parameter to solo mining is the receiving Bitcoin address which changes the miner's Merkel Root?
No. The fact that the address is unique is just how you know that you aren't working on the same data as anybody else. Other "variable parameters" are the timestamp, the specific set of transactions that you include in your block, and the exact order of those transactions. A change in any of those parameters results in a completely different block for you to work on.
So, if you change the mining address, you can change the Merkel Root and the subsequent region of guesses the miner will choose to try and solve the block, therefore shifting your luck?
You won't shift your luck at all, you'll just change the block you're trying to solve. You'll still have the same probability on each hash you attempt.
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I have not worked out any real maths on this to see if it would give you a slight edge or not.
It wouldn't. Think about rolling a die 100 times, can you improve your odds of rolling a six on any single roll if you skip the first 5 and/or last 5 rolls?