Oooh, quantitative finance ... haven't seen that in a while. Note my exposure to this is basically internet blog posts and probably some random textbooks, so probably not up to date. But...
1. Is bitcoin actually experiencing less volatility on a percentage basis as adoption goes up? This could be argued both ways -
On one hand, 30-day rolling annualized volatility has not shown a decrease; rather the process seems to be cyclical (apologies for the hasty graph and badly labeled data -- this is a btc-e timeseries):
30-day autocorrelation is also not that interpretable:
On the other hand, the magnitude of moves and drawdowns seem to have decreased - thus longer term volatility measures may indicate a decrease. Depends on your measurement.
2. Should lower volatility be a policy goal?
On one hand, for bitcoin to be adpoted as a currency, current volatility is clearly unacceptable. But would anti-vol measures ("plunge protection teams", circuit breakers, derivatives) trade short term stability for catastrophic long-term consequences (in other words, would they increase kurtosis)? Haven't done the math, but I suspect bitcoin is even more Levy-distributed (aka not normal distributed) than stocks. Also, due to decentralization, would any anti-vol measures actually be effective? You can't exactly trade stocks the same way you can trade bitcoin.
Just my thoughts.