for gpu mining it does not matter if the cards are sli or not, however for Bitcoin gpu mining is dead due to the high difficulty.
As far as mining rigs, always take into consideration the mining difficulty increase, using a calculator that takes that into account, like
http://www.vnbitcoin.org/bitcoincalculator.php or bitcoinwindsdom.
Avoid BFL by all means unless if getting your mining rig a year late is acceptable.
The best bet is kncminer which is risky do to their high price and quick rising in difficulty.
Safest bet buy the bitcoins.