Obviously, once you got mining going now is the time for overclocking and fine-tuning.
Read those to get yourself up to speed:
GUI Miner threadHardware subforumWhen in doubt, use the Search function && RTFM.
Report
specific issues here.
Once you get familiarized with mining I suggest you switch to cgminer which is the most advanced miner currently available.
CGminer threadIf your machine is going to be used as a dedicated mining rig:
(1)
Never use crossfire. Make sure the crossfire connector is removed.
(2) Don't overclock that CPU. You aren't going to need it. You might also opt to disable half of the cores - that will increase your power efficiency.
(3) There's no good explanation to stick with Windows.